Tetrakis(μ-4-tert-butylbenzoato)-κ4 O:O′;κ3 O,O′:O′;κ3 O:O,O′-bis[aqua(4-tert-butylbenzoato-κ2 O,O′)(4-tert-butylbenzoic acid-κO)neodymium(III)]
نویسندگان
چکیده
The reaction of neodymium nitrate and 4-tert-butyl-benzoic acid (tBBAH) in aqueous solution yielded the dinuclear title complex, [Nd(2)(C(11)H(13)O(2))(6)(C(11)H(14)O(2))(2)(H(2)O)(2)], which has non-crystallographic C(i) symmetry. The two Nd(III) ions are linked by two bridging and two bridging-chelating tBBA ligands with an Nd⋯Nd separation of 4.0624 (5) Å. Moreover, each Nd(III) ion is coordinated by one chelating tBBA ion, one monodentate tBBAH ligand and one water mol-ecule. The nine-coordinated Nd(III) ion is in a distorted tricapped trigonal-prismatic environment. The mol-ecules are linked into infinite chains along the c axis by inter-molecular O-H⋯O hydrogen bonds. Three of the tert-butyl groups are disordered over two sets of sites with equal occupancies.
منابع مشابه
Tetrakis(μ-4-tert-butylbenzoato)-κ3 O:O,O′;κ3 O,O′:O′;κ4 O:O′-bis[aquabis(4-tert-butylbenzoato-κ2 O,O′)(4-tert-butylbenzoic acid-κO)praseodymium(III)]
The reaction of praseodymium nitrate and 4-tert-butyl-benzoic acid (tBBAH) in aqueous solution yielded the dinuclear title complex, [Pr(2)(C(11)H(13)O(2))(6)(C(11)H(14)O(2))(2)(H(2)O)(2)], which has non-crystallographic C(i) symmetry. The two Pr(III) ions are linked by two bridging and two bridging-chelating tBBA ligands, with a Pr⋯Pr separation of 4.0817 (9) Å. Each Pr(III) ion is nine-coordin...
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In the centrosymmetric binuclear title complex, [Ce(2)(C(9)H(9)O(3))(6)(C(12)H(8)N(2))(2)], the two Ce(III) ions are linked by four 2-phen-oxy-propionate groups in bi- and tridentate bridging modes. Each Ce(III) ion is nine-coordinated by one 1,10-phenanthroline mol-ecule, two O atoms from a chelating carboxyl-ate, two O atoms derived from a μ(3)-carboxylate and two O atoms derived from two μ(2...
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In the centrosymmetric binuclear title complex, [Dy(2)(C(9)H(9)O(3))(6)(C(12)H(8)N(2))(2)], the two Dy(III) ions are linked by four 2-phen-oxy-propionate (L) groups through their bi- and tridentate bridging modes. Each Dy(III) ion is nine-coordinated by one 1,10-phenanthroline mol-ecule, one bidentate carboxyl-ate group and four bridging carboxyl-ate groups in a distorted DyN(2)O(7) monocapped ...
متن کاملTetrakis(μ-2-phenoxypropionato)-κ3 O,O′:O′;κ3 O:O,O′,κ4 O:O′-bis[(1,10-phenanthroline-κ2 N,N′)(2-phenoxypropionato-κ2 O,O′)praseodymium(III)]
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متن کاملTetrakis[μ-2-(4-hydroxyphenyl)acetato]-κ3 O,O′:O;κ3 O:O,O′-bis{aqua(4,4′-bipyridine-κN)bis[2-(4-hydroxyphenyl)acetato-κ2 O,O]neodymium(III)} monohydrate
The title complex, [Nd(2)(C(8)H(7)O(3))(6)(C(10)H(8)N(2))(2)(H(2)O)(2)]·H(2)O, contains two Nd atoms, six 4-hy-droxy-phenyl-acetate (hpaa) anions, two 4,4'-bipyridine mol-ecules (bipy) and two water mol-ecules; an additional water mol-ecule of solvation is also present in the crystal structure. Each of the Nd(III) ions is nine-coordinated by seven O atoms from four hpaa ligands, an N atom from ...
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عنوان ژورنال:
دوره 67 شماره
صفحات -
تاریخ انتشار 2011